Molecular Geometry and Bonding Theories

Molecular Geometries


Molecular shapes, or geometries, are critical to molecular recognition and function.

Molecular Geometries

The Lewis structure of carbon tetrachloride:

However, the Lewis structure provides no information about the shape of the molecule

The structure of a molecule is defined by:

In carbon tetrachloride:

Carbon tetrachloride is tetrahedral in structure:

Molecular Geometries of ABn molecules

A central atom A is bonded to two or more B atoms

These structures can generally be predicted, when A is a nonmetal, using the "valence-shell electron-pair repulsion model (VSEPR)


1996 Michael Blaber